Add a new startup application
Open your registry and find the key [HKEY_CURRENT_USER\Software\Microsoft\Windows\CurrentVersion\Run].
For each program you want to start automatically create a new string value using a descriptive name, and set the value of the string to the program executable.
For example, to automatically start Notepad, add a new entry of "Notepad"="c:\windows\notepad.exe".
Remove a startup application
If you're trying to remove a program and can not find it in the StartUp folder (usually C:\WINDOWS\Start Menu\Programs\StartUp), then it may be launching from one of the registry keys below. To remove it, delete the value associated with the program you want to remove.
[HKEY_LOCAL_MACHINE\Software\Microsoft\Windows\CurrentVersion\Run]
[HKEY_LOCAL_MACHINE\Software\Microsoft\Windows\CurrentVersion\RunOnce]
[HKEY_LOCAL_MACHINE\Software\Microsoft\Windows\CurrentVersion\RunServices]
[HKEY_LOCAL_MACHINE\Software\Microsoft\Windows\CurrentVersion\RunServicesOnce]
[HKEY_LOCAL_MACHINE\Software\Microsoft\Windows NT\CurrentVersion\Winlogon\Userinit]
[HKEY_CURRENT_USER\Software\Microsoft\Windows\CurrentVersion\Run]
[HKEY_CURRENT_USER\Software\Microsoft\Windows\CurrentVersion\RunOnce]
[HKEY_CURRENT_USER\Software\Microsoft\Windows\CurrentVersion\RunServices]
[HKEY_CURRENT_USER\Software\Microsoft\Windows\CurrentVersion\RunServicesOnce]
[HKEY_CURRENT_USER\Software\Microsoft\Windows NT\CurrentVersion\Windows]
It may also be loaded from the [Load] or [Run] sections of your WIN.INI file, found in the Windows directory.